|
|
(4Z)-2-oxohept-4-enedioate + H2O <=> (4S)-4-hydroxy-2-oxoheptanedioate
|
4.2.1
4.2.1.163
2-oxo-hept-4-ene-1,7-dioate hydratase
|
–
–
|
|
BRENDA:
BR51626
KEGG:
R04131
MetaCyc:
HYDROXYHEPTA-DIENEDIOATE-HYDROXY-RXN
|
|
|
|
(4S)-4-hydroxy-2-oxoheptanedioate <=> succinate_semialdehyde + pyruvate
|
4.1.2.20
2-dehydro-3-deoxyglucarate aldolase
4.1.2.52
4-hydroxy-2-oxoheptanedioate aldolase
4.1.3.39
4-hydroxy-2-oxovalerate aldolase
|
–
–
–
|
|
BRENDA:
BR50711
KEGG:
R01645
MetaCyc:
4-HYDROXY-2-KETOPIMELATE-LYSIS-RXN
SABIO-RK:
1783
|
|
|
|
5-Carboxymethyl-2-hydroxymuconate <=> (3E,5R)-5-carboxy-2-oxohept-3-enedioate
|
5.3.3.10
5-carboxymethyl-2-hydroxymuconate Delta-isomerase
|
–
|
|
BRENDA:
BR244;
BS1083
KEGG:
R04379
MetaCyc:
5.3.3.10-RXN
|
|
|
|
4-hydroxyphenylacetate + O2 + FADH2 <=> H+ + 3,4-Dihydroxyphenylacetate + H2O + FAD
|
1.14.14.9
4-hydroxyphenylacetate 3-monooxygenase
|
–
|
|
BRENDA:
BR40424
MetaCyc:
RXN-8505
|
|
|
|
5-carboxymethyl-2-hydroxymuconate_semialdehyde + NAD+ + H2O <=> H+ + 5-Carboxymethyl-2-hydroxymuconate + NADH
|
1.1.1.312
2-hydroxy-4-carboxymuconate semialdehyde hemiacetal dehydrogenase
1.2.1.60
5-carboxymethyl-2-hydroxymuconic-semialdehyde dehydrogenase
|
–
–
|
|
BRENDA:
BR29416
KEGG:
R04418
MetaCyc:
CHMS-DEHYDROGENASE-RXN
SABIO-RK:
4105
|
|
|
|
H+ + (3E,5R)-5-carboxy-2-oxohept-3-enedioate <=> (4Z)-2-oxohept-4-enedioate + CO2
|
4.1.1.68
5-oxopent-3-ene-1,2,5-tricarboxylate decarboxylase
|
–
|
|
BRENDA:
BR329;
BS1577
KEGG:
R04133
MetaCyc:
4.1.1.68-RXN
|
|
|
|
O2 + 3,4-Dihydroxyphenylacetate <=> H+ + 5-carboxymethyl-2-hydroxymuconate_semialdehyde
|
1.13.11.15
3,4-dihydroxyphenylacetate 2,3-dioxygenase
|
–
|
|
BRENDA:
BR40487
KEGG:
R03303
MetaCyc:
1.13.11.15-RXN
SABIO-RK:
3120
|
|
|
|
succinate_semialdehyde + NADP+ + H2O <=> NADPH + succinate + H+
|
1.1.1.21
aldose reductase
1.2.1.16
succinate-semialdehyde dehydrogenase [NAD(P)+]
1.2.1.24
succinate-semialdehyde dehydrogenase (NAD+)
1.2.1.26
2,5-dioxovalerate dehydrogenase
1.2.1.79
succinate-semialdehyde dehydrogenase (NADP+)
|
–
–
–
–
–
|
|
BRENDA:
BR29388
KEGG:
R00714
MetaCyc:
RXN0-5293;
SUCCSEMIALDDEHYDROG-RXN
SABIO-RK:
1086
|
|